The problem I see with using a power transformer as an audio transformer is the non-flat frequency response. Secondly the proper core material in an audio transformer is M6 steel which contains some silicon to increase permeability. In addition nickel is added to increase the permeability further and reduce the hysteresis. higher permeability means less windings required for coupling. Less windings means lower resistance and lower power loss, Bad hysteresis creates distortion. A typical audio transformer for a tube amp will have distortion below .1%. I have never measured a power transformer at high frequencies. But if harmonic distortion is bad so will be the inter-modulation distortion and the sound will be harsh. Maybe the core material in toroidal transformer is more ideal, I have no experience with that. But I do know that toroidal cores saturate more easily, so if there is any offset on the output of the power amp, and also because of the lower winding resistance, as fairly large current could flow decreasing the ability for high output. I am assuming with big panels you want pretty big output?
I would really be interested if someone had run some distortion numbers using a power transformer as a step-up. If transformers were so easy, then people would not spend a fortune on moving coil step-up transformers. I know its low signal level and needs tons of shielding, but low distortion is a primary driver there.
Of course for the adventurous, you buy an EI core and wind your own. The secondary can be very thin wire, since the electrostatic panels don't load the transformer much and impedance is very high.
I had a set of Accustats at one time. They used a transformer with a higher ratio to get the bass boost and crossed it over in the bass region. Worked very well.